Light, wavelengths and color, and everything we perceive through our eyes,
are intricately related.
There are many different wavelengths around, ranging from 400 nanometers to
800 nanometers. And each wavelength gives us a perception of a different
color.
Of all these different wavelengths/colors, there are three primary colors and
each of these primary colors has one secondary color:
Primary Color
Secondary Color
Blue
Yellow
Red
Cyan
Green
Magenta
Primary and Secondary colors cancel each other out: a blue wavelength
accompanied by a yellow wavelength of the same intensity will give us the
perception of seeing white.
Combinations of primary and secondary colors
+
=
+
=
+
=
However if the blue wavelength is unaccompanied by its yellow counterpart, then
we will have the perception of seeing blue.
What would make the color "Yellow" disappear?
Absorption by objects: when light hits an object, the object will, depending
on its composition, absorb some of the wavelengths and in varying degrees. If
all the light that hits the object manages to escape, then we see white; and
if none of the light manages to get out, then we see black.
So basically what we perceive as the color of an object is actually the part
of the light that escaped from the object: by playing around with all the
wavelengths and all the different degrees of absorption for each of them, we
see the infinite variety of colors around us.
About Diamonds
An absolutely perfectly pure, "white" diamond would be composed of
carbon atoms arranged in a perfect tetrahedral lattice. With this atomic
structure, none of the light would be absorbed, the diamond would return all
the light it receives and would be perceived as completely colorless.
However such diamonds don't exist: during their crystallization phase,
diamonds lie 150 to 200 km under the earth's crust, and are subjected to
pressures of about 70,000 kg/cm2 (about 1,000,000 pounds/in2) and to
temperatures ranging from 1300 to 2000°C. (2300 to 3600°F). Under these
conditions, diamonds lose their atomic integrity: their orderly tetrahedral
structure is twisted and they come to absorb other types of atoms. As a
result, they do not reflect all the light they receive - some of the
wavelengths are absorbed and the diamond takes on some color.
Diamonds are classified depending on what happened to them during their
crystallization phase.
Type I Diamonds
Are
diamonds that ended up absorbing a detectable quantity of nitrogen atoms,
which absorb blue light.
Type Ia:
If the nitrogen atoms are clustered together within the carbon lattice, then
the diamond is said to be a Type Ia diamond.
Because these diamonds absorb blue light, they can have a pale yellow color.
98% of diamonds are Type Ia
Type Ib: If the nitrogen atoms are evenly spread out throughout the carbon lattice, then the diamond is said to be a Type
Ib diamond. These diamonds absorb green light as well as
blue light, and have a darker color than type Ia
diamonds. Depending on the precise concentration and spread of the nitrogen
atoms, these diamonds can appear deep yellow ("canary"), orange,
brown or greenish. Less then 0.1% of diamonds belong to Type Ib.
Type II Diamonds
Are
diamonds that absorbed no, or very few, nitrogen atoms.
Type IIa: These diamonds can be considered as the
"purest of the pure" - they contain no, or minuscule amounts of
impurities and are usually colorless. Unless, that is, the carbon
tetrahedrons that make up the diamond were twisted and bent out of shape
while the diamond rose to the surface of the earth. An imperfect carbon
lattice will make the diamond absorb some light, which will give it a yellow,
brown or even pink or red color. 1-2% of diamonds belong to Type IIa.
Type IIb: These diamonds contain no nitrogen - but
they contain boron, which absorbs red, orange and yellow light. These
diamonds therefore usually appear to be blue, although they can also be grey
or nearly colorless. All naturally blue diamonds belong to Type IIb, which makes up 0.1% of all diamonds.
Summary of diamond classification
Type I
Ia
Ib
Prevalence
98%
0.1%
Color centers
Clustered
nitrogen atoms
Isolated nitrogen
atoms
Color
Colorless Yellow
Orange
Orange Yellow
Brown
Type II
IIa
IIb
Prevalence
1-2%
0.1%
Color centers
No specific color center
Boron atoms
Color
Colorless Yellow Brown Pink Purple
Blue Gray
What about green diamonds?
Green
diamonds are a separate case: these diamonds can contain clustered nitrogen
atoms or they can contain no nitrogen atoms - what gives them their color is
that they have been bombarded by nuclear rays during their growth. This
bombardment makes them absorb magenta wavelengths, which gives them their
green color. These diamonds are extremely rare.